- A mild and efficient protocol for the conversion of carboxylic acids to ...🔍
- Publications🔍
- Decarboxylative Elimination of Carboxylic Acids to Give Alkenes🔍
- Photoredox catalysis harvesting multiple photon or electrochemical ...🔍
- A solution to the anti|Bredt olefin synthesis problem🔍
- Radical Mediated Decarboxylation of Amino Acids via ...🔍
- Irradiation|induced palladium|catalyzed decarboxylative ...🔍
- Hydroalkylation of Olefins to form Quaternary Carbons🔍
Decarboxylative Elimination for the Systhesis of Olefins Via ...
A mild and efficient protocol for the conversion of carboxylic acids to ...
... olefins by a catalytic decarbonylative elimination reaction. ... SYNTHESIS OF ALKENES BY OXIDATIVE DECARBOXYLATION OF CARBOXYLIC ACIDS ...
Publications | Tunge Research Group - The University of Kansas
90. Cartwright, K. C.; Tunge, J. A. "Decarboxylative Elimination of N-Acyl Amino Acids via Photoredox/Cobalt Dual Catalysis" ACS Catal. 2018, 8, ...
Decarboxylative Elimination of Carboxylic Acids to Give Alkenes
Alkenes are valuable products and intermediates in organic synthesis, and new methods for their synthesis are always interesting research ...
Photoredox catalysis harvesting multiple photon or electrochemical ...
Cinnamyl alcohol could either be reduced on the alkene functionality to 39l or further reduced to 39m while reductive ring-opening of trans-2-phenylcyclopropane ...
A solution to the anti-Bredt olefin synthesis problem - Science
... olefins using silyl halide precursors. ... The result further suggests that Kobayashi elimination to form the ABO likely occurs through a ...
Radical Mediated Decarboxylation of Amino Acids via ... - MDPI
Herein, we present the first examples of amino acid decarboxylation via photochemically activated carbonyl sulfide (COS) elimination of the corresponding ...
Irradiation-induced palladium-catalyzed decarboxylative ... - Nature
Generation of alkenes through decarboxyolefination of alkane carboxylates has significant synthetic value in view of the easy availability ...
Hydroalkylation of Olefins to form Quaternary Carbons - ChemRxiv
activated alkenes: synthesis of novel 20'-vinblastine analogues. ... Formation of C(sp3)–C(sp3) bonds through nickel-catalyzed decarboxylative olefin.
Decarboxylative cross-coupling - Wikipedia
Decarboxylative cross coupling reactions are chemical reactions in which a carboxylic acid is reacted with an organic halide to form a new carbon-carbon ...
Decarboxylation - Master Organic Chemistry
Decarboxylation occurs readily in beta-keto acids and in malonic acid derivatives. · The reaction proceeds through a cyclic, concerted transition ...
Decarboxylative Acylation of Carboxylic Acids: Reaction ...
Ketones serve as one of the most critical building blocks in organic synthesis, involving numerous functional group transformations.
PRIME PubMed | Direct Aroylation of Olefins through a Cobalt ...
PubMed journal article: Direct Aroylation of Olefins through a Cobalt/Photoredox-Catalyzed Decarboxylative and Dehydrogenative Coupling with α-Oxo Acids.
Since many carboxylic acids and their derivatives are readily available and inexpensive, using these compounds as starting materials in organic synthesis is an ...
Sharpless olefin synthesis | SpringerLink
Olefin synthesis from the syn-oxidative elimination of o-nitrophenyl selenides, which may be prepared using o-nitrophenyl selenocyanate and Bu3P, ...
Olefination via Cu-Mediated Dehydroacylation of Unstrained Ketones.
The dehydroacylation of ketones to olefins is realized under mild conditions, which exhibits a unique reaction pathway involving aromatization-driven CC ...
Elimination for the Synthesis of Olefins. Shu-Wei Wu,† Jia-Li Liu† and Feng ... The reaction was carried out using a microwave tube (10 mL) equipped with a.
copper and subsequent reductive elimination to generate chloro- or fluoro(hetero)arenes. ... Synthesis of Biaryls via · Catalytic Decarboxylative ...
Synthesis of substituted alkenes - Organic Chemistry Portal
The combination of Pd(PPh3)2Cl2 with Xantphos efficiently catalyzes a decarboxylative Heck reaction of vinyl arenes and vinyl heteroarenes with aliphatic N-( ...
Cyclopropanation of Alkenes - Master Organic Chemistry
The simplest method is treatment of diazomethane (CH2N2) with light (“photolysis”) to give methylene carbene, which adds to alkenes to form ...
Reaction Investigation and Mechanistic Study | CCS Chemistry
The one-pot decarboxylative acylation at the gram scale from two different carboxylic acids and the late-stage application for the synthesis of complex ketones ...