- Discovery of biomimetic transamination as a general synthetic ...🔍
- NHCs|Catalyzed Enantioselective Synthesis of Biaryl Axially Chiral ...🔍
- The potential of converting carbon dioxide to food compounds via ...🔍
- Bisguanidinium|pyridoxal phosphate catalysed asymmetric reactions🔍
- Asymmetric biomimetic transamination of α|keto amides to peptides🔍
- Spotting trends in organocatalysis for the next decade🔍
- Enzyme|Inspired Axially Chiral Pyridoxamines Armed with a ...🔍
- Biomimetic and organocatalytic approaches to oxidation catalysis*🔍
Vitamin B6|Based Biomimetic Asymmetric Catalysis
Discovery of biomimetic transamination as a general synthetic ...
... asymmetric synthesis of fluorinated amines and amino acids. Ukr. Bioorg ... Biochemistry, 1937, 2, 859-874. (a) Martell, A.E. Vitamin B6-catalyzed ...
NHCs-Catalyzed Enantioselective Synthesis of Biaryl Axially Chiral ...
... asymmetric catalysis, currently relies on the utilization of transition metal catalysts ... Vitamin B6-Based Biomimetic Asymmetric Catalysis. Acc.
The potential of converting carbon dioxide to food compounds via ...
On the basis of the asymmetric catalytic function of vitamin B6, Cai et al. developed a variety of chiral biomimetic catalytic systems ...
Bisguanidinium-pyridoxal phosphate catalysed asymmetric reactions
... Vitamin B6, that serves as a versatile cofactor in numerous enzymatic reactions across diverse biological pathways. We propose to study biomimetic catalysis ...
Asymmetric biomimetic transamination of α-keto amides to peptides
Metzler, D. E., Ikawa, M. & Snell, E. E. A general mechanism for vitamin B6- catalyzed reactions. J. Am. Chem. Soc. 76, 648–652 ( ...
Spotting trends in organocatalysis for the next decade
vitamin B6, enabled a highly enantio- and diastereo-selective. Mannich ... Carbonyl catalysis enables a biomimetic asymmetric Mannich reaction. Science ...
Spotting trends in organocatalysis for the next decade - PMC
... based catalysts and develop truly metal-free processes. The ... Carbonyl catalysis enables a biomimetic asymmetric Mannich reaction.
Enzyme-Inspired Axially Chiral Pyridoxamines Armed with a ...
2020. TLDR. This work shows that chiral aldehyde catalysis based on a ... Chiral Pyridoxal-Catalyzed Asymmetric Biomimetic Transamination of α-Keto Acids.
Biomimetic and organocatalytic approaches to oxidation catalysis*
and alkaloid-based phase-transfer catalysts for the asymmetric epoxidation of enones. ... date for the catalytic asymmetric epoxidation of vitamin K. 3. (3) ...
Vitamin B6-Based Biomimetic Asymmetric Catalysis. Xiao Xiao and Baoguo Zhao. Acc. Chem. Res., 2023, 56, 1097. DOI: 10.1021/acs.accounts.3c00053. Catalytic ...
Asymmetric α-C(sp3)−H allylic alkylation of primary alkylamines by ...
Carbonyl catalysis enables a biomimetic asymmetric Mannich reaction. ... Vitamin B6-based biomimetic asymmetric catalysis. Acc. Chem. Res. 56 ...
Poster Title (14pt Tahoma Bold)
Vitamin B6-Based Biomimetic Asymmetric Catalysis. Baoguo Zhao*. College of Chemistry and Materials Science, Shanghai Normal University, 100 Guilin. Road ...
Asymmetric biomimetic transamination of α-keto amides to peptides.
Based on the “condensation-transamination” process, a new strategy for the synthesis of peptides also can be developed. As illustrated in Fig. 5b, the methyl ...
A comprehensive review of flow chemistry techniques tailored to the ...
... based catalysis [167]. In 2014, Isogai ... Scheme 86: Continuous-flow asymmetric epoxidation of derivatives of 359 exploiting a biomimetic iron catalyst.
Aldehyde Catalysis: New Options for Asymmetric Organocatalytic ...
In nature, vitamin B6 bearing an aldehyde group can activate amino acids through α-functionalization, and it has been employed in a vast array ...
Biomimetic Photoexcited Cobaloxime Catalysis in Organic Synthesis
fossil-based to bio-based chemicals, promoting sustainabil- ity. By ... Asymmetric Catalysis. The first application of cobaloxime in asymmetric ...
Vitamin B6 | Linus Pauling Institute | Oregon State University
Contents Summary Function Nervous system Hemoglobin synthesis Tryptophan metabolism Hormone function Nucleic acid synthesis Deficiency The RDA Disease ...
A biomimetic SH2 cross-coupling mechanism for quaternary sp3 ...
Begley, Mechanistic Studies on CysS - A Vitamin B ... Zhang, Synthesis and biological evaluation of a novel sigma-1 receptor antagonist based ...
asymmetric catalysis, and indicated principles for designing new organocatalytic reactions based ... Biomimetic Concepts to. Applications in ...
Biomimetic oxygenations catalyzed by metalloporphyrins and ...
... Asymmetric catalysis with chiral organocopper-copper arenethiolates ... based on organozirconium and organocopper chemistry.