A Ni4O4|cubane|squarate coordination framework for molecular ...

A Ni4O4-cubane-squarate coordination framework for molecular ...

Molecular recognition is a fundamental function of natural systems that ensures biological activity. This is achieved through the sieving ...

A Ni4O4-cubane-squarate coordination framework for molecular ...

A Ni4O4-cubane-squarate coordination framework for molecular recognition. Qingqing Yan. Shuyi An. Liang Yu. Shenfang Li. Xiaonan Wu. Siqi Dong. Shunshun Xiong.

Chemistry | Nature Communications

A Ni4O4-cubane-squarate coordination framework for molecular recognition. Materials for multifunctional molecular recognition are essential in industry. Here ...

Magnetic Phase Transitions in a Ni 4 O 4 -Cubane-Based Metal ...

Magnetic Phase Transitions in a Ni4O4-Cubane-Based Metal–Organic Framework ... coordination network exhibits magnetic ordering at 23.9 K as ...

Magnetic Phase Transitions in a Ni 4 O 4 -Cubane-Based Metal ...

5 %) starting at 150 °C is due to loss of one water molecule coordinated to Ni3 (calc. 5.06 %) in the framework. At higher temperatures the ...

An unexpected cubane-like nickel(II) tetranuclear complex bridged ...

Ligand Effect on the Single-Molecule Magnetism of Tetranuclear Co(II) Cubane. 2017, Inorganic Chemistry. Four novel frameworks built by imidazole-based ...

Magnetic Phase Transitions in a Ni4O4-Cubane-Based Metal

5%) starting at 1508C is due to loss of one water molecule coordinated to Ni3 (calc. 5.06%) in the framework. At higher temperatures the mass remains ...

Flexibility of cubane-like Cu4I4 framework - PubMed

... the cubane-like framework is ... MeSH terms. Coordination Complexes / chemistry*; Crystallography, X-Ray; Luminescence*; Models, Molecular; Molecular Structure ...

Coordination-Adaptive Molecular Platform for Catalytic Water ...

Enzymes utilize adaptive frameworks to accommodate diverse structural and electronic requirements of intermediates, enhancing the catalysis.

A chiral alkali metal capped Ni4 cubane complex: Synthesis ...

Additionally, two water molecules (O17 and O18) and three acetate anions (O13, O14, O15 and O19) complete the coordination sphere of the Ni(II) ...

A highly stable metal–organic framework with cubane-like clusters ...

... a kind of electron-acceptor for the construction of molecular cages, luminescent and photochromic materials. In this paper, a novel and Coordination Networks.

A Three-Dimensional Coordination Framework with a Ferromagnetic ...

In compound 1, the asymmetric unit contains one crystallographically independent Ni(II) ion, one chromate anion, one coordinated water molecule, ...

Stabilization of reactive Co4O4 cubane oxygen-evolution catalysts ...

... molecular cluster by covalent immobilization in a porous metal–organic framework. ... Proposed local coordination environment of framework ...

3D Framework Containing Cu4Br4 Cubane as Connecting Node ...

... coordination framework controlled by adjusting the symmetry of its secondary building unit. Journal of Molecular Structure 2013, 1046 , 15-20.

Synthesis, Structural Characterization and Ligand-Enhanced Photo ...

... the squarate ligands and coordinated water molecules. (d) The 3D ... Framework Coordination Polymers of Tetra(4-carboxyphenyl)porphyrin and Lanthanide ...

A Tetranuclear Ni(II)-Cubane Cluster Molecule Build by Four µ 3

The remaining 30 complexes comprise compounds with acv-metal (M) coordination bonds (the number of compounds reported for each metal ion is indicated in ...

Squarate-Calcium Metal–Organic Framework for Molecular Sieving ...

However, ensuring full reaction is difficult, as the solvent from the environment can become coordinated with calcium atoms, which alters the equation (Tu et al ...

A zirconium squarate metal-organic framework with modulator ...

A zirconium squarate metal-organic framework with modulator-dependent molecular sieving properties. ... frameworks (IR-MOFs), porous coordination networks…

4.6: Coordination Frameworks - Chemistry LibreTexts

Examples of how the building blocks shown in Figure 4.6.2 might be used to prepare molecular polyhedra and coordination networks are depicted ...

Synthesis, structural characterization and thermal stability of a 2D ...

Intra-and inter-layer hydrogen bonding interactions between the uncoordinated oxygen atoms of squarate and coordinated water molecules in the framework provide ...