Direct Decarboxylative Functionalization of Carboxylic Acids via O|H ...

Direct Decarboxylative Functionalization of Carboxylic Acids via O ...

Herein, we report a direct decarboxylative functionalization of aliphatic carboxylic acids using N-xanthylamides. The unique reactivity of ...

Direct Decarboxylative Functionalization of Carboxylic Acids via O-H ...

Decarboxylative functionalization via hydrogen atom transfer offers an attractive alternative to standard redox approaches to this important ...

Direct Decarboxylative Functionalization of Carboxylic Acids via O ...

A complementary approach to decarboxylative functionalization would involve O─H hydrogen-atom transfer (HAT) of a carboxylic acid to generate a ...

Direct Decarboxylative Functionalization of Carboxylic Acids via O ...

These catalytic studies support a mechanism involving direct OÀ H hydrogen atom transfer, which complements standard redoxbased methods for decarboxylative ...

Direct Decarboxylative Functionalization of Carboxylic Acids via O ...

Direct Decarboxylative Functionalization of Carboxylic Acids via O–H Hydrogen Atom Transfer. https://doi.org/10.1021/jacs.9b10825 ·. Journal: Journal of the ...

Organic charge-transfer complex induces chemoselective ...

General functionalization using aryl carboxylic acids ... direct decarboxylation of aryl carboxylic acids for general functionalization.

Decarboxylative Acylation of Carboxylic Acids

in decarboxylative functionalization of carboxylic acids. The one ... Direct C(sp3)–H Acylation Enabled by Metallaphotoredox. Catalysis ...

Pd-catalyzed decarboxylative dehydrogenation of alkanecarboxylic ...

An efficient platform for decarboxylative functionalization of carboxylic acids using ... H Bond Functionalization, Chem. – Eur. J., 2016 ...

Decarboxylative functionalization of carboxylic acids. - ResearchGate

Transition‐metal‐catalyzed decarboxylative cross‐coupling reaction provides a powerful method for the construction C−C, C−N, C−O bonds, which have great impact ...

Carboxylic Acids as Adaptive Functional Groups in ...

Whereas recent decarboxylative functionalization methodologies often necessitate preactivated aliphatic carboxylic acids in the form of redox- ...

Free Carboxylic Acids: The Trend of Radical Decarboxylative ...

... decarboxylative functionalization of free carboxylic acids. ... High deuteration incorporations were obtained when D2O was used instead of H2O ( ...

Divergent process for the catalytic decarboxylative thiocyanation ...

... functionalization of benzylic C–H positions and redox active esters. ... carboxylic acids using an organic photocatalyst. The study started ...

Tandem dehydrogenation-olefination-decarboxylation of cycloalkyl ...

... carboxylic acids via palladium catalyzed decarboxylative multifold C–H activation ... functionalization of carboxylic acids without ...

A Unified Approach to Decarboxylative Halogenation of (Hetero)aryl ...

Herein, we report a general catalytic method for direct decarboxylative halogenation of (hetero)aryl carboxylic acids via ligand-to-metal charge ...

Copper-Catalyzed Decarboxylative Functionalization of Conjugated ...

Developing decarboxylative functionalization strategies that utilize carboxylic acids ... using other radical species besides O-acyl-N ...

Light‐Induced Direct Decarboxylative Functionalization of Aromatic ...

The generation of these reactive species via direct decarboxylation of inexpensive and readily available aromatic carboxylic acids is an attractive goal ...

Visible Light-Mediated Direct Decarboxylative C–H ...

The direct visible light-mediated C–H alkylation of heteroarenes using aliphatic carboxylic acids is reported. This mild method proceeds at low catalyst ...

Visible-light photosensitized aryl and alkyl decarboxylative carbon ...

Decarboxylative C–H. Arylation of Benzoic Acids under Radical Conditions. Org ... Photodecarboxylative chlorination of carboxylic acids via their benzophenone ...

Template for Electronic Submission to ACS Journals - Infoscience

... H functionalization and decarboxylative functionalization ... Direct. Decarboxylative Functionalization of Carboxylic Acids via O-H. Hydrogen Atom Transfer.

Modular, stereocontrolled Cβ–H/Cα–C activation of alkyl carboxylic ...

Thus, a C–H activation of ubiquitous carboxylic acids followed by their decarboxylative functionalization provides modular access to difunctionalized carbon ...