Flavin|mediated dual oxidation controls an enzymatic Favorskii|type ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type ...

Structural and functional studies reveal how the bacterial flavoenzyme EncM catalyses the oxygenation–dehydrogenation dual oxidation of a ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type ...

We show that EncM maintains an unexpected stable flavin-oxygenating species, proposed to be a flavin-N5-oxide, to promote substrate oxidation ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type ...

Here we report that the bacterial flavoenzyme EncM catalyses the peroxyflavin-independent oxygenation-dehydrogenation dual oxidation of a highly reactive poly(β ...

[PDF] Flavin-mediated dual oxidation controls an enzymatic ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement · R. Teufel, A. Miyanaga, +6 authors. B. Moore · Published in Nature 27 October ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type ...

Cyclization; Anti-Bacterial Agents; Protein Conformation; Isotope Labeling; Flavins; Biocatalysis; Models, Chemical; Streptomyces; Flavoproteins ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement. Robin Teufel, Akimasa Miyanaga, Quentin Michaudel, Frederick Stull, Gordon ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type ...

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement ... Authors: Robin Teufel; Akimasa Miyanaga; Quentin Michaudel; Frederick Stull ...

Flavin-mediated dual oxidation con - H1 Connect

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement. ... Favorskii-type rearrangement through unprecedented flavin-N5-oxide species.

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type ...

Downloadable (with restrictions)! Structural and functional studies reveal how the bacterial flavoenzyme EncM catalyses the oxygenation–dehydrogenation dual ...

129. Flavin-Mediated Dual Oxidation Controls an Enzymatic ...

Flavin-Mediated Dual Oxidation Controls an Enzymatic Favorskii-type Rearrangement, Nature 2013, 503, 552-556. Leave a Reply Cancel reply. Your email address ...

Scholars - Texas A&M University

Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement. | Academic Article individual record · Overview · Identity · Additional ...

Enzymatic control of dioxygen binding and functionalization ... - PNAS

We have now shown how a flavoenzyme interacts with O2 and controls the formation of an oxygenating species as key to oxidative catalysis. This ...

Structural and chemical trapping of flavin‐oxide intermediates ...

Though reactive flavin‐N5/C4α‐oxide intermediates can be spectroscopically profiled for some flavin‐assisted enzymatic reactions, ...

Oxygen-transfer reactions by enzymatic flavin-N5 oxygen adducts ...

First, the oxidized flavin cofactor (Flox) is reduced in the reductive half reaction by a hydride equivalent donated from external (typically reduced ...

Enzymatic control of dioxygen binding and functionalization ... - PNAS

(2013) Flavin-mediated dual oxidation controls an enzymatic Favorskii- type rearrangement. Nature 503:552–556. 22. Teufel R (2017) Flavin ...

Enzymatic spiroketal formation via oxidative rearrangement of ...

Typically, these enzymes catalyze aromatic hydroxylation reactions via an electrophilic flavin-C4a-hydroperoxide oxygenating species, while some ...

Three Rings to Rule Them All: How Versatile Flavoenzymes ...

; Moore, B. S. Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement. Nature 2013, 503, 552– 556, DOI: 10.1038 ...

Publications | Department of Pharmaceutical Sciences | University of ...

(2018) “Enzymatic control of dioxygen binding and functionalization of the flavin ... (2013) “Flavin-mediated dual oxidation controls an enzymatic Favorskii-type ...

Flavin adenine dinucleotide - Wikipedia

"Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement". Nature. 503 (7477): 552–6. Bibcode:2013Natur.503..552T. doi:10.1038 ...

Insights into the enzymatic formation, chemical features, and ... - OUCI

Teufel, Flavin-mediated dual oxidation controls an enzymatic Favorskii-type rearrangement, Nature, № 503, с. 552 https://doi.org/10.1038/nature12643; Ewing ...