Influence of Lone|Pair Cations on the Intra|octahedral Distortion in ...

Influence of Lone-Pair Cations on the Intra-octahedral Distortion

Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral. Distortion in d0 Transition Metals. P. Shiv ...

Asymmetric Cation Coordination in Oxide Materials: Influence of ...

Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition Metals.

Influence of Lone-Pair Cations on the Intra-octahedral Distortion in ...

Request PDF | Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 ...

Asymmetric Cation Coordination in Oxide Materials: Influence of ...

... Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition Metals ... and a lone-pair cation (Sn2+, Se4+, Te4+, etc.) are examined to investigate the ...

Asymmetric cation coordination in oxide materials: Influence of lone ...

Asymmetric cation coordination in oxide materials: Influence of lone-pair cations on the intra-octahedral distortion in d 0 transition metals. Author: SHIV ...

Metal cation s lone-pairs increase octahedral tilting instabilities in ...

Previous studies concluded that the lone-pair stereochemical activity primarily leads to the off-centering motion of the metal cation, and the ...

Crystal growth and structure of V 2 V Se 2 IV O 9 - ScienceDirect.com

Asymmetric cation coordination in oxide materials: Influence of lone-pair cations on the intra-octahedral distortion in d⁰ transition metals. 2004 ...

Metal cation s lone-pairs increase octahedral tilting instabilities in ...

Thus, our normalization procedure helps to normalize the effect of preferential orientations of the different measured crystals and makes a ...

Disentangling the effects of structure and lone-pair electrons in the ...

It was proposed that this combination derives from the ns2 electron configuration of octahedral cations and associated pseudo-Jahn–Teller effect ...

Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d ...

Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d⁰ Transition Metals. DOI ...

Metal cation s lone-pairs increase octahedral tilting instabilities in ...

Here, we show that the lone-pair stereochemical activity contributes to strong octahedral tilting instabilities that induce liquid-like behavior ...

5.8: Jahn-Teller Effect - Chemistry LibreTexts

Jahn-Teller distortion of a d9 octahedral transition metal complex. The tetragonal distortion lengthens the bonds along the z-axis as the bonds ...

Jahn-Teller Distortions, Cation Ordering and Octahedral Tilting in ...

This paper examines the influence of octahedral tilting and cation ordering on orbital ordering in perovskites containing. J±T cations. Systematic comparisons ...

On the crystal chemistry of inorganic nitrides

Halasyamani P. S. Asymmetric cation coordination in oxide materials: Influence of lone-pair cations on the intra-octahedral distortion in d0 transition metals.

The second-order Jahn-Teller effect - ScienceDirect.com

Asymmetric cation coordination in oxide materials: Influence of lone-pair cations on the intra-octahedral distortion in d⁰ transition metals. 2004 ...

Chemistry, Structure, and Function of Lone Pairs in Extended Solids

38 Halasyamani, P. S. Asymmetric Cation Coordination in Oxide Materials: Influence of. Lone-Pair Cations on the Intra-Octahedral Distortion in d0 Transition ...

Different mechanism of response of asymmetric lone pair electrons ...

Asymmetric cation coordination in oxide materials: Influence of lone-pair cations on the intra-octahedral distortion in d0 transition metals.

A Chemical-Pressure-Induced Phase Transition Controlled by Lone ...

Special attention is paid to discriminating the role of the lone pair Sn2+ cation from the structural distortive effect along the Mo/W ...

Nonlinear Optical Switching Driven by the Lone Pair Electron Effect ...

The typical lone pair effect was observed in (quinuclidinium)GeCl3, in which the phase transition mechanism is similar to that in CsGeX3, except ...

Lone Pairs, Hidden and Otherwise - UCSB MRL

Cation s states are narrow and largely unmixed with anion p in cases when the lone pair is not stereochemically active (cf. the inert pair effect). Scalar.