Introducing Stable Radicals into Molecular Machines

We highlight our research on the art and science of introducing radical-pairing interactions into functional systems, from prototypical molecular switches to ...

Introducing Stable Radicals into Molecular Machines - PubMed

Ever since their discovery, stable organic radicals have received considerable attention from chemists because of their unique optical, ...

Introducing Stable Radicals into Molecular Machines - PMC - NCBI

Typically, because stable organic radical species contain at least one unpaired electron, they exhibit unique behavior associated with magnetic, ...

[PDF] Introducing Stable Radicals into Molecular Machines

By taking the radical cationic state of 1,1′-dialkyl-4,4′-bipyridinium (BIPY•+) as an example, research on the art and science of introducing ...

Harnessing Radicals: Advances in Self‐Assembly and Molecular ...

The potential of radical interactions in the development of artificial molecular machines (AMMs) are also discussed. These AMMs, powered by ...

Persistent and Stable Organic Radicals: Design, Synthesis, and ...

By introducing substituents in different positions, the modulated electronic structures with perturbed resonance forms can be realized and ...

Harnessing Radicals: Advances in Self‐Assembly and Molecular ...

The review concludes by comparing AMMs to biological molecular machines, offering insights into future directions. This overview underscores the ...

Publications – Stoddart Mechanostereochemistry Group

Introducing stable radicals into molecular machines, (Y. Wang, M. Frasconi, J. F. Stoddart), ACS Cent. Sci. 2017, 3, 927—935. Full Text. 1128. Noninvasive ...

Engineering stable radicals using photochromic triggers - Nature

Long-standing radical species have raised noteworthy concerns in organic functional chemistry and materials. However, there remains a ...

Select Publications by Professor Fraser Stoddart | UNSW Research

'Supramolecular Tessellations ... Wang Y; Frasconi M; Stoddart JF, 2017, 'Introducing Stable Radicals into Molecular Machines', ACS Central Science, 3, pp.

Stable organic radical qubits and their applications in quantum ...

Stable organic radicals behave as tunable electron spin qubits with room-temperature quantum coherence. •. Molecular structures, environment, ...

Multi-objective goal-directed optimization of de novo stable organic ...

Advances in the field of goal-directed molecular optimization offer the promise of finding feasible candidates for even the most challenging ...

Radical-pairing-induced molecular assembly and motion. - Abstract

Introducing Stable Radicals into Molecular Machines. Wang Y, Frasconi M, Stoddart JF · ACS Cent Sci, 3(9):927-935, 14 Aug 2017. Cited by: 26 articles | PMID ...

Tuning the stability of organic radicals: from covalent approaches to ...

If dynamicity can be introduced in modulating the stability of radicals, a tunable stability can be achieved, and thus the radicals are able ...

A Quantitative Metric for Organic Radical Stability and Persistence ...

We demonstrate this approach in identifying Pareto-optimal candidates for stable organic radicals. Introduction. From the initial discovery of free radicals to ...

A Light-Stimulated Molecular Switch Driven by Radical-Radical ...

Introducing Stable Radicals into Molecular Machines. Article. Full-text available. Aug 2017. Yuping Wang · Marco ...

Tuning the stability of organic radicals: from covalent approaches to ...

Bohan Tang, Jiantao Zhao, +1 author. Xi Zhang · Published in Chemical Science 4 January 2020 · Chemistry, Materials Science.

Molecular machines | Feature - Chemistry World

The thread can be divided into two main parts – the viologen unit, with which the macrocycle forms a stable radical complex when the system is ...

Radical (chemistry) - Wikipedia

They also play a key role in the intermediary metabolism of various biological compounds. Such radicals can even be messengers in a process dubbed redox ...

Nobel Lecture: Mechanically Interlocked Molecules (MIMs)

on a firm footing before introducing [28] them into molecular switches in the first instance. ... employ radical chemistry to form a stable [2]rotaxane-like ...