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NHCs|Catalyzed Enantioselective Synthesis of Biaryl Axially Chiral ...


NHCs-Catalyzed Enantioselective Synthesis of Biaryl Axially Chiral ...

We report a NHC-catalyzed atropoenantioselective amidation reaction between axially prochiral biaryl dialdehydes and amides, enabling the efficient synthesis ...

NHCs-Catalyzed Enantioselective Synthesis of Biaryl Axially Chiral ...

The synthesis of biaryl axially chiral amides and their derivatives, which have demonstrated potential as additives or catalysts in ...

NHC-catalyzed atropoenantioselective synthesis of axially chiral ...

Axially chiral biaryl amino-alcohols play a pivotal role in organic synthesis and drug discovery. However, only a very few enantioselective ...

NHCs-Catalyzed Enantioselective Synthesis of Biaryl Axially Chiral ...

Download Citation | On Oct 22, 2024, Yingtao Wu and others published NHCs-Catalyzed Enantioselective Synthesis of Biaryl Axially Chiral ...

NHC-catalyzed atropoenantioselective synthesis of axially chiral ...

Axially chiral biaryl amino-alcohols play a pivotal role in organic synthesis and drug discovery. However, only a very few enantioselective ...

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd ...

(59) Since then, a variety of ligands (48, 60-66) have been examined for the asymmetric Pd-catalyzed Suzuki coupling reaction. Recent noteworthy ...

Enantioselective Synthesis of Axially Chiral Diaryl Ethers via NHC ...

The NHC-catalyzed enantioselective synthesis of axially chiral diaryl ethers was developed via desymmetrization of prochiral 2- ...

Enantioselective Synthesis of Axially Chiral Biaryl Monophosphine ...

Enantioselective metal-catalyzed Suzuki coupling has become one of the most used protocols in the synthesis of axially chiral biaryls. (5) In ...

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd ...

We report efficient syntheses of axially chiral biaryl amides in yields ranging from 80−92%, and with enantioselectivity in the range 88−94% ee employing an ...

Enantioselective Synthesis of Axially Chiral Benzothiophene ...

The N-heterocyclic carbene catalyzed enantioselective de novo synthesis of axially chiral benzothiophene/benzofuran-fused biaryls from enals ...

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd ...

Palladium-catalyzed reactions involving Kumada, Negishi, Hiyama and Suzuki-Miyaura cross-coupling have emerged as one of the most powerful and general means of ...

Catalyzed Enantioselective Synthesis of Axially Chiral Biaryls | CCS ...

A Pd(II)-catalyzed enantioselective tandem C–H/C–C activation for the synthesis of axially chiral biaryls is described.

Catalyzed Enantioselective Synthesis of Axially Chiral Biaryls

A Pd(II)-catalyzed enantioselective tandem C–H/C–C activation for the synthesis of axially chiral biaryls is described.

Enantioselective Synthesis of Axially Chiral Biaryls by the Pd

We report efficient syntheses of axially chiral biaryl amides in yields ranging from 80−92%, and with enantioselectivity in the range 88−94% ee employing an ...

Enantioselective construction of ortho-sulfur- or nitrogen-substituted ...

This coupling protocol also enabled the highly enantioselective synthesis of axially chiral biaryl compounds possessing ortho-alkenyl (3c) ...

Article Enantioselective Carbon-Carbon Bond Cleavage for Biaryl ...

Enantioselective synthesis of axially chiral biaryls by the Pd-catalyzed Suzuki−Miyaura reaction: Substrate scope and quantum mechanical ...

NHC-catalyzed atropoenantioselective synthesis of axially chiral ...

NHC-catalyzed atropoenantioselective synthesis of axially chiral biaryl amino alcohols via a cooperative strategy · Gongming Yang, Donghui Guo, +1 author. Jian ...

NHC‐catalyzed synthesis of benzenes and axially chiral biaryls.

Based on the continuous interest in harnessing NHC catalysis for asymmetric construction of bioactive chiral molecules, we herein report a carbene-catalyzed ...

Synthesis of axially chiral biaryl compounds by asymmetric catalytic ...

This review will summarize the different strategies imagined by chemists to control such chirality, focusing on asymmetric catalytic processes with transition ...

Recent advances in the synthesis of axially chiral biaryls via ...

used as privileged ligands in asymmetric catalysis. Over the past few decades, the efficient synthesis of axially chiral biaryls has been a research topic ...