Photoredox|Catalysed Decarboxylative Alkylation of N ...

Photoredox‐Catalysed Decarboxylative Alkylation of N ...

In the spotlight: Enabled by merging an iridium photoredox catalyst with a stoichiometric amount of Brønsted acid or a catalytic amount of ...

Photoredox‐Catalysed Decarboxylative Alkylation of N ...

Decarboxylative alkylation of N-heteroarenes with N-(acyloxy)phthalimides was achieved under mild conditions.

Photoredox-Catalysed Decarboxylative Alkylation of N ... - PubMed

An iridium photoredox catalyst in combination with either a stoichiometric amount of Brønsted acid or a catalytic amount of Lewis acid is capable of ...

Visible-Light Photoredox-Catalyzed Decarboxylative Alkylation of ...

Diverse alkylations of various heteroarenes were achieved with 0.3 equiv of n-Bu4NOAc by taking advantage of CO2 release (Scheme 1, eq 4). The ...

Visible Light Photoredox-Catalyzed Decarboxylative Alkylation of 3 ...

Importantly, pyridines, the most prevalent aromatic N-heterocycles in bioactive compounds, (33) could be readily introduced while tolerating ...

Photoredox-Catalyzed Decarboxylative Alkylation of N-Heteroarenes

ative alkylation of N-heteroarenes using a leaving group assisted redox-active ester in combination with an iridium photocatalyst. This Minisci-type.

Photoredox-Catalysed Decarboxylative Alkylation of N ...

A mild, practical protocol for the decarboxylative alkylation of heteroarenes has been accomplished via iron photocatalysis.

Photoredox-Catalysed Decarboxylative Alkylation of N ...

Photoredox-Catalysed Decarboxylative Alkylation of N-Heteroarenes with N-(Acyloxy)phthalimides. Cheng WM 1 ,. Shang R 1 ,. Fu MC 1 ,. Fu Y 1. Author information ...

Photoredox-catalyzed stereoselective alkylation of enamides with N ...

Stereoselective β-C(sp2)–H alkylation of enamides with redox-active N-hydroxyphthalimide esters via a photoredox-catalyzed decarboxylative cross-coupling ...

The Direct Decarboxylative N-Alkylation of Azoles, Sulfonamides ...

This platform employs visible-light-mediated photoredox catalysis and an iodine(III) reagent to generate carbocation intermediates directly from ...

Photoredox-Catalysed Decarboxylative Alkylation of N ...

Request PDF | Photoredox-Catalysed Decarboxylative Alkylation of N-Heteroarenes with N-(Acyloxy)phthalimides | An iridium-photoredox catalyst in combination ...

Photoredox catalysis enabled alkylation of alkenyl carboxylic acids ...

2]octane (DABCO) efficiently catalyzed dual decarboxylative couplings between alkenyl carboxylic acids and N-(acyloxy)phthalimides derived from aliphatic ...

Photoredox-Catalyzed Decarboxylative Alkylation of N-Heteroarenes

A leaving group assisted redox-active ester is described to enable direct coupling of amino acid with N-heteroarenes and the efficient and sustainable ...

Photoredox-Catalyzed Decarboxylative Alkylation of Silyl Enol ...

A photoredox-catalyzed decarboxylative alkylation of silyl enol ethers provides diverse functionalized aryl alkyl ketones in good yields using N-(acyloxy ...

Utilization of photocatalysts in decarboxylative coupling of carboxylic ...

In 2018, Fu, Opatz and Jin demonstrated that an Ir/Ru photocatalyst in combination with a Lewis acid could catalyse the decarboxylative alkylation of N- ...

Photocatalytic decarboxylative alkylations mediated by ... - Science

Moreover, the phosphine/iodide-based photoredox system catalyzes Minisci-type alkylation of N-heterocycles and can operate in tandem with chiral ...

Photoredox-Catalyzed Decarboxylative Alkylation of Silyl Enol ...

Diverse functionalized aryl alkyl ketones were afforded in modest to good yields using N-(acyloxy)phthalimide as an easy access alkyl radical source under mild ...

Enantioselective construction of quaternary N-heterocycles by ...

In this article, we describe the highly enantioselective palladium-catalysed decarboxylative allylic alkylation of readily available lactams.

Photoredox Decarboxylative Alkylation/(2+2+1) Cycloaddition of 1,7 ...

Photoredox Decarboxylative Alkylation/(2+2+1) Cycloaddition of 1,7‐Enynes: A Cascade Approach Towards Polycyclic Heterocycles Using N‐(Acyloxy)phthalimides as ...

Photoredox‐Catalysed Decarboxylative Alkylation of N ...

An iridium photoredox catalyst in combination with either a stoichiometric amount of Brønsted acid or a catalytic amount of Lewis acid is capable of ...