The enigmatic reaction of flavins with oxygen

The enigmatic reaction of flavins with oxygen - ScienceDirect.com

Reaction of reduced flavin with oxygen. The reaction starts with transfer of one electron from the reduced flavin to oxygen, to form a caged radical pair ...

The enigmatic reaction of flavins with oxygen - PubMed

The reaction of flavoenzymes with oxygen remains a fascinating area of research because of its relevance for reactive oxygen species (ROS) generation.

The enigmatic reaction of flavins with oxygen - Cell Press

at room temperature, molecular oxygen is in the triplet state. This implies that chemical reactions of O2 with organic molecules such as the ...

The enigmatic reaction of flavins with oxygen - Bates LibrarySearch

The reaction of flavoenzymes with oxygen remains a fascinating area of research because of its relevance for reactive oxygen species (ROS) generation.

The enigmatic reaction of flavins with oxygen

The reaction of flavoenzymes with oxygen remains a fascinating area of research because of its relevance for reactive oxygen species (ROS) generation.

The enigmatic reaction of flavins with oxygen. - Abstract - Europe PMC

The reaction of flavoenzymes with oxygen remains a fascinating area of research because of its relevance for reactive oxygen species (ROS) generation.

Figure 1 from The enigmatic reaction of flavins with oxygen.

Figure 1. Reaction of reduced flavin with oxygen. The reaction starts with transfer of one electron from the reduced flavin to oxygen, to form a caged ...

The enigmatic reaction of flavins with oxygen | Request PDF

... The mechanism of the reaction of oxygen with reduced flavin is one of the most widely studied yet enigmatic reactions in biochemistry. The reaction is ...

The enigmatic reaction of flavins with oxygen - Altmetric

The enigmatic reaction of flavins with oxygen · Trends in Biochemical Sciences, July 2012 · 10.1016/j.tibs.2012.06.005 · 22819837 · Pimchai Chaiyen, Marco W.

The enigmatic reaction of flavins with oxygen

The enigmatic reaction of flavins with oxygen. Pimchai Chaiyen, Marco W. Fraaije, Andrea Mattevi. Trends in Biochemical Sciences. Volume 37 Issue 9 Pages 373 ...

Oxidation of Flavin by Molecular Oxygen: Computational Insights ...

When involved in oxidation of the enzyme's substrate, flavin is reduced in the chemical step (reductive half-reaction as experienced by flavin) ...

Oxidation of Flavin by Molecular Oxygen: Computational Insights ...

Because molecular oxygen exists as a triplet in its electronic ground state, whereas the products are singlets, the reaction is accompanied by hopping between ...

New frontiers in flavin-dependent monooxygenases - ScienceDirect

Flavin-dependent monooxygenases (FMOs)1 use oxygen and an external reductant, such as NADPH, to oxygenate a large number of compounds. The ...

Protonation status and control mechanism of flavin–oxygen ...

Bacterial luciferase (Lux) is the only known flavin-dependent monooxygenase capable of generating light. Lux reactions catalyze the oxidation of ...

Enzymatic control of dioxygen binding and functionalization ... - PNAS

However, details of the preceding reaction of O2 with the reduced flavin cofactor that gives rise to these oxygenating species remain scarce. We have now shown ...

Same Substrate, Many Reactions: Oxygen Activation in Flavoenzymes

Oxygen-utilizing enzymes tightly control the reactions involving O2 mostly by modulating the reactivity of their cofactors. Flavins are ...

Alteration of Electron Acceptor Preferences in the Oxidative Half ...

Flavin-dependent oxidases oxidize substrates with the reduction of flavin (reductive half-reaction), and the reduced flavin is reoxidized by oxygen, liberating ...

Same Substrate, Many Reactions: Oxygen Activation in Flavoenzymes

The physical and chemical principles of flavin-based chemistry have been investigated widely. In the following pages we summarize the state of ...

Oxygen-transfer reactions by enzymatic flavin-N5 oxygen adducts ...

Oxygen-transfer reactions by enzymatic flavin-N5 oxygen adducts—Oxidation is not a must ; Journal: Current Opinion in Chemical Biology, 2024, p. 102464.

‪Pimchai Chaiyen‬ - ‪Google Scholar‬

The enigmatic reaction of flavins with oxygen. P Chaiyen, MW Fraaije, A Mattevi. Trends in biochemical sciences 37 (9), 373-380, 2012. 251, 2012. Multiple ...