Direct Decarboxylative Functionalization of Carboxylic Acids via O|H ...

Modular, stereocontrolled Cβ–H/Cα–C activation of alkyl carboxylic ...

Thus, a C–H activation of ubiquitous carboxylic acids followed by their decarboxylative functionalization provides modular access to difunctionalized carbon ...

Iron-mediated modular decarboxylative cross-nucleophile coupling

We report a photochemical method for the direct decarboxylative functionalization of carboxylic acids with a wide range of simple carbon-, oxygen-, and ...

Visible Light-Enabled Direct Decarboxylative N-Alkylation.

... Carboxylic Acids via Photoredox Catalysis. ... Late-Stage Functionalization of Arylacetic Acids by Photoredox-Catalyzed Decarboxylative Carbon-Heteroatom Bond ...

Radical Decarboxylative Carbon–Nitrogen Bond Formation - MDPI

... directly using carboxylic acids as the reactants. (2). Another ... Recent advances in C–S bond formation via C–H bond functionalization and decarboxylation.

Decarboxylative Acylation of Carboxylic Acids: Reaction ...

In this context, several research groups– have reported elegant examples of metallaphotoredox-catalyzed C(sp3)-H acylation with amides, anhydrides, or activated ...

Catalyst-controlled functionalization of carboxylic acids by ... - Nature

... decarboxylation to direct product ... Decarboxylative conjunctive cross‐coupling of vinyl boronic esters using metallaphotoredox catalysis.

Coumarin-3-carboxylic acid: C3/C4-functionalizations and ...

Coumarin-3-carboxylic acid; functionalization; cyclization; heterocycles; decarboxylative ... 2] annulation via the C4–H bond cleavage of coumarin-3-carboxylic ...

Decarboxylative Alkenylation of Imidazo[1,2-a]pyridines Using α,β ...

Decarboxylative Alkenylation of Imidazo[1,2-a]pyridines Using α,β-Unsaturated Carboxylic Acids via Pd-Catalyzed C–H Functionalization. Saurabh Kumar. ,. Neha ...

Decarboxylative Elimination for the Systhesis of Olefins Via ...

Carboxylic acids are abundant in nature, bench stable, cheap, and readily available and thus are ideal feedstocks for organic synthesis. Direct decarboxylation ...

HYDROGEN BONDING-ENABLED SITE-SELECTIVE C(sp3)

H. H. H. O. O. H. H. H. SPT. H. H. H. H ... (20) Na, C. G.; Ravelli, D.; Alexanian, E. J. Direct Decarboxylative Functionalization of Carboxylic Acids via O–H ...

Advances in Decarboxylative Oxidative Coupling Reaction

Copper Mediated. Decarboxylative Direct C-H Arylation of Heteroarenes with Benzoic. Acids. ... Oxocarboxylic Acids via Palladium-Catalyzed C−H ...

A Unified Approach to Decarboxylative Halogenation of (Hetero)aryl ...

Although thermal decarboxylative functionalization of aryl carboxylic acids ... carboxylic acids via ligand-to-metal charge transfer. This strategy ...

Iron-mediated modular decarboxylative cross-nucleophile coupling

Here, we report a photochemical method for the direct decarboxylative functionalization of carboxylic acids with a wide range of simple carbon-, ...

Photocatalytic Decarboxylative Hydroxylation of Carboxylic Acids ...

This paper discloses the first example of photocatalytic direct decarboxylative hydroxylation of carboxylic acids, accomplished under extremely mild reaction ...

Decarboxylative Cyanation and Azidation of Carboxylic Acids

Wu, H. Jiang, Palladium-catalyzed denitrogenative synthesis of aryl ketones from arylhydrazines and nitriles using O2 as sole oxidant, J. Org.

Visible-Light-Induced Decarboxylative Functionalization of ...

Article citations · Mechanisms for radical reactions initiating from N-hydroxyphthalimide esters. · Direct conversion of carboxylic acids to free thiols via ...

Decarboxylation - Organic Chemistry Portal

A mild decarboxylative reduction of naturally abundant carboxylic acids such as α-amino acids and α-hydroxy acids has been achieved via visible-light photoredox ...

A general method for photocatalytic decarboxylative hydroxylation of ...

Direct Decarboxylative Functionalization of Carboxylic Acids via O–H Hydrogen Atom Transfer · Davide Ravelli. Journal of the American Chemical Society, 2019.

CAREER: Copper Catalyzed Oxidative Decarboxylative Coupling ...

... Direct Functionalization of Arenes. NSF ... carbon (C-C) bonds from carboxylic acids through oxidative decarboxylative coupling reactions.

Photocatalytic Direct Decarboxylation of Carboxylic Acids to ... - X-MOL

Multiple transformations of copolymers were achieved, including derivatization with olefin units, functionalization with pendent alkenes, and ...